4 wire kelvin test

when measuring very low resistance(miliohm), it is necessary to perform 4 wire test in order to get an accurate reading. However, can opamp(comparator) provide a better accuracy when come to resitance comparison?(ie does opamp able to differentiate a 11miliohm and 10miliohm resistor? provided using the same amount of current supply to the resistor). since the open loop gain of an opamp can reach 1x10^6 which suggest it capable to amplify a very small value to a significant value.
Theoretically, it should working but anyone know does it applicable even in practical?